Tailor-made Catalysts for Asymmetric Hydrogenation of Ketones

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概要

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• Asymmetric hydrogenation of ketones catalyzed by XylBINAP/chiral diamine-Ru (II), To1BI-NAP/PICA-Ru (II), η<SUP>6</SUP>-arene/TsDPEN-Ru (II), and MsDPEN-CpIr (III) complexes affords a variety of sec-ondary alcohols with high enantioselectivity. Complete conversion is attainable with a low catalyst loading. The high catalyst efficiency is rationalized by a novel “metal-ligand cooperative mechanism.”

• 社団法人 有機合成化学協会の論文
• 2007-11-01

著者

• Ohkuma Takeshi

  Division Of Chemical Process Engineering Graduate School Of Engineering Hokkaido University

関連論文

• Asymmetric hydrogenation of ketones: Tactics to achieve high reactivity, enantioselectivity, and wide scope
• Tailor-made Catalysts for Asymmetric Hydrogenation of Ketones

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