Multi-Curve Fitting Analysis of Temperature-Dependent $I$-$V$ Curves of Poly-Hexathienylphenanthroline-Bridged Nanogap Electrodes
スポンサーリンク
概要
- 論文の詳細を見る
Stable junctions were obtained by preparing polymeric hexathienylphenanthroline wires coordinated to [RuII(bpy)2](PF6)2 groups directly in Au electrode nanogaps by electropolymerization. Reproducible nonlinear and strongly temperature-dependent curves, similar to those found for self-assembled $\pi$-conjugated dithiols and diisocyanides inside nanoholes, were obtained rather than a tunneling behavior commonly found in alkanethiol self-assembled monolayers. This is the first time that a consistent series of data are collected for a polymer and interpreted based on a multicurve fitting method, based on the linear combination of tunneling, Frankel-Pool and hopping mechanims, indicating that various independent conduction pathways are present in the junctions.
- Japan Society of Applied Physicsの論文
- 2004-05-01
著者
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OGAWA Takuji
Research Center for Molecular-Scale Nanoscience, Institute for Molecular Science
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Ogawa Takuji
Research Center For Molecular Nanoscience Institute For Molecular Science Okazaki National Research
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Endo Hiroaki
Research Center For Molecular Nanoscience Institute For Molecular Science Okazaki National Research
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Araki Koiti
Research Center for Molecular Nanoscience, Institute for Molecular Science, Okazaki National Researc
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Tanaka Hirofumi
Research Center for Molecular Nanoscience, Institute for Molecular Science, Okazaki National Researc
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Araki Koiti
Research Center For Molecular Nanoscience Institute For Molecular Science Okazaki National Research
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Tanaka Hirofumi
Research Center For Molecular Nanoscience Institute For Molecular Science Okazaki National Research
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- Multi-Curve Fitting Analysis of Temperature-Dependent $I$-$V$ Curves of Poly-Hexathienylphenanthroline-Bridged Nanogap Electrodes
- Simple Preparation Method for Supramolecular Porphyrin Arrays on Mica Using Air–Water Interface