低原子価希土類の新展開
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概要
- 論文の詳細を見る
Samarium diiodide (SmI<SUB>2</SUB>) is widely employed as a useful single-electron reducing agent in organic synthesis because of its adequate reducing ability and suitable solubility in organic solvent such as THF. Although samarium diiodide itself can reduce aldehydes, ketones, alkyl bromides, and iodides, the reduction requires long period of heating and stirring. To enhance the reducing ability of SmI<SUB>2</SUB>, therefore, several unique methods have been developed recently, which include the addition of ligands, the combination with other metals, and photoactivation. This review deals with the recent advance in low-valent rare earth metal-assisted new reduction systems.
- 社団法人 有機合成化学協会の論文
- 2003-03-01