Chromium Nitride Precipitation Behavior in Weld Heat-affected Zone of High Nitrogen Stainless Steel

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High nitrogen stainless steels (HNS) containing about 1 mass% (%) nitrogen without adding Mn were manufactured by pressurized electro-slag remelting method. The chromium nitride precipitation behaviors at the weld heat-affected zone (HAZ) of HNS with different compositions were investigated. We also evaluated the localized corrosion resistance of the welded joints.The nitride precipitates were identified as Cr2N containing a small amount of Mo and Fe by TEM/EDS analyses. Time-temperature-precipitation curves of some HNS were obtained. It was found that for 23Cr-4Ni-2Mo-1N steel, aging for 2 s in the temperature range between 1173 K and 1373 K caused Cr2N precipitation and decreased the critical pitting corrosion temperature (CPT) in the 6% FeCl3 solution. Precipitation was delayed to 4 s by decreasing the nitrogen content from 1 to 0.8% and was further slightly delayed to over 5 s by adding the pre-deformation followed by the thermal treatment of 23Cr-4Ni-2Mo-0.8N steel.Precipitation at the HAZ was accelerated by a continuous thermal cycle test compared to the prediction based on the additivity rule, and that the existence of a ferritic phase affected acceleration was estimated.Joints welded by laser and minimum heat input conditioned plasma arc welding showed a 348 K CPT in a 6% FeCl3 solution and no crevice corrosion occurred at 308 K in artificial seawater. The CPT dropped notably against holding time above 1073 K at the HAZ. The CPT drop was slightly relieved by decreasing nitrogen content in the base metal from 1 to 0.8%.
社団法人日本鉄鋼協会の論文
2002-12-15

Chromium Nitride Precipitation Behavior in Weld Heat-affected Zone of High Nitrogen Stainless Steel

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