Formation and Reaction of Acyl Substituted Nitrile Ylide through the Rh_2(OAc)_4-Catalyzed Reaction of α-Diazocarbonyl Compounds with Benzonitrile

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概要

• 論文の詳細を見る
• 1992-11-05

著者

• IBATA Toshikazu

  Department of Chemistry, Graduate School of Science, Osaka University

• Ibata T

  Department Of Chemistry Graduate School Of Science Osaka University

• Ibata Toshikazu

  Institute Of Chemistry College Of General Education Osaka University

• FUKUSHIMA Kazuaki

  Institute of Chemistry, College of General Education, Osaka University

• Fukushima Kazuaki

  Institute Of Chemistry College Of General Education Osaka University

関連論文

• Asymmetric Cyclopropanation and Aziridination Reactions of Olefins Catalyzed by Cu(I)-Binaphthyldiimine Complexes
• Stereocontrol in a Ytterbium Triflate-Catalyzed 1,3-Dipolar Cycloaddition Reaction of Carbonyl Ylide with N-substituted Maleimides and Dimethyl Fumarate
• Regioselectivity in Formal[3+2]Cycloaddition Reaction of 5-Alkoxyoxazoles with Diethyl Oxomalonate and 2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone
• Synthesis of 2, 5-Dihydro-1, 2, 4-oxadiazoles through Formal [3+2] Cycloaddition of Oxazoles with Nitrosobenzene Derivatives
• Regio-Control of Formal [3 + 2] Cycloadditions of 5-Alkoxyoxazoles with Diethyl Oxomalonate
• Formation of 5-Alkoxy-2-aminooxazoles and Their Novel Reactivity : Equilibrium with Nitrile Ylide
• Reaction of Mono-, Di-, and Trichloronitrobenzenes with N-Methyl Substituted Cyclic Tertiary Amines under High Pressure
• Nucleophilic Substitution Reaction of Aromatic Chlorides with Cyclic Tertiary Amines under High Pressure
• Formation and Reaction of Azomethine Ylide by the Reaction of Cu(acac)2-ketocarbenoids with 1,1-Diphenylmethanimine
• The Nucleophilic Substitution Reaction of p-Chloronitrobenzene with N-Substituted Cyclic Amines under High Pressure
• Formation and Reaction of Acyl Substituted Nitrile Ylide through the Rh_2(OAc)_4-Catalyzed Reaction of α-Diazocarbonyl Compounds with Benzonitrile
• Molecular structure of the exo-Diels-Alder-adduct of 5-methoxy-2-methyl-4-(p-nitrophenyl)oxazole with N-methylmaleimide.
• Synthesis and molecular structure of the 2:1-cycloadduct of 1-methoxy-2-benzopyrylium-4-olate with acenaphthylene.
• The BF3 catalyzed decomposition of diazo compounds in the presence of carbonyl compounds.
• The reaction of diazo ketones in the presence of metal chelates. VIII. The stereochemistry of the 1,3-dipolar cycloaddition of 1-methoxy-2-benzopyrylium-4-olates to ethylenic dipolarophiles.
• Formation and reaction of oxazoles. Synthesis of N-substituted 2-(aminomethyl)oxazoles.
• Aromatic nucleophilic substitution of halobenzenes with amines under high pressure.
• Reaction of diazo ketones in the presence of metal chelates. VII. 1,3-Dipolar cycloaddition of 1-methoxybenzo[c]pyrylium-4-olate with acetylenic dipolarophiles.
• The acid catalyzed decomposition of diazo compounds. I. Synthesis of oxazoles in the BF3 catalyzed reaction of diazo carbonyl compounds with nitriles.
• Formation of 1,3-oxathiole-2-thione and 1,2,4-trithiolane derivatives by the catalytic reaction of .ALPHA.-diazocarbonyl compounds with carbon disulfide.
• Formation and molecular structure of the 2:1-adducts of 1-alkoxy-2-benzopyrylium-4-olates with carbon disulfide.
• The Diels-Alder reactions of 2-alkyl-5-methoxy-4-(p-nitrophenyl)oxazoles with ethylenic, acetylenic, and azo-type dienophiles.
• The Acid-catalyzed Decomposition of α-Diazo β-Hydroxy Ketones
• Formation and reaction of carbonyl ylides. 1,3-Dipolar cycloaddition of 2-benzopyrylium-4-olates with carbonyl compounds.
• The high pressure Diels-Alder reactions of 5-methoxy-2-methyl-4-(p-nitrophenyl)oxazole with ethylenic dienophiles.
• The acid-catalyzed decomposition of diazo carbonyl compounds. II. Synthesis of 2- or 5-heteroatom-substituted oxazoles.

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