反応性電極を用いる新しい有機合成反応

概要

論文の詳細を見る
Some synthetic electroorganic reactions promoted by chemically reactive electrodes (CRE) have recently been exploited and CRE is one of the most attractive new techniques in electroorganic chemistry (EOC). Altohugh the definition of CRE is not always clear at present, the role of electrode in CRE method is quite different from that in the conventional EOC. Namely, the role of electrode in the conventional EOC is generally just a donor or acceptor of an electron and it is not involved in the organic reaction as a reagent. On the other hand, in CRE method, some electrode mterials made of chemically reactive materials such as Mg, Al, and Zn are involved in the reaction as reagents and promote unique reactions which are not attained under the usual conditions of EOC. In this article some synthetic reactions using CRE are described, and the main contents of the article are as follows : 1) Electroreuction of aliphatic ester and amide and related C-C bond forming reactions, 2) Si-Si and Ge -Ge bonds formation reactions and their application to the synthesis of ploysilane and polygermane high polymers, 3) Coupling of dienes and styrenes with aliphatic esters, 4) Reduction of aromatic compounds, 5) Generation of highly reactive metals (Electrogenerated metals).
社団法人有機合成化学協会の論文
1996-08-01