Comparative Studies on the Combustion Kinetics of Chars Prepared from Brown and Bituminous Coals under Air (O_2/N_2) and Oxy-fuel (O_2/CO_2) Conditions
スポンサーリンク
概要
- 論文の詳細を見る
This paper deals with the application of a solid-gas reaction model which can describe the combustion and gasification mechanism for air (O_2/N_2) and oxy-fuel (O_2/CO_2) conditions. Loy Yang brown coal was used as a sample after pyrolysis, together with Newlands coal as bituminous coal for comparison of coal ranks. By carrying out the thermogravimetric analysis (TGA) run under non-isothermal conditions, chemical reaction rates of partial oxidation reaction and gasification reaction were estimated. Heat and mass transfer between the single pulverized char particle and gas were numerically simulated, thus, overall reaction rate including mass transfer rate, chemical reaction rate could be evaluated. In the low temperature region, the reaction rate is mainly controlled by the chemical reaction, on the other hand, it becomes dominated by mass transfer, (diffusion as well as convection effects), in high temperature region. Using this solid-gas reaction model, burn-off time of each char was also estimated under the various conditions, i.e., air (5% O_2/N_2) and oxy-fuel (5% O_2/CO_2) conditions with consideration of absence and presence of CO_2 gasification reaction effect.
著者
関連論文
- No.30 微粉炭燃焼において生成ガスが酸化剤の物質移動に及ぼす影響の数値解析(燃焼,NOx)
- Experimental and Numerical Investigation of Effect of Coal Rank on Burn-off Time in Pulverized Coal Combustion
- No.19 常圧管状炉を落下する微粉炭チャー粒子の非定常熱・物質移動解析(研究発表)
- No.5 種々の温度と湿度条件下における褐炭の基礎的乾燥特性と乾燥速度式の定式化(研究発表)
- Comparative Studies on the Combustion Kinetics of Chars Prepared from Brown and Bituminous Coals under Air (O_2/N_2) and Oxy-fuel (O_2/CO_2) Conditions
- O?/CO?系における部分酸化反応を伴うチャー粒子表面へのO?の物質移動速度
- 燃焼モデル(石炭基礎講座(17))
- 熱工学