Comparison of Ferroelectric and Strain Properties between BaTiO3- and BaZrO3-Modified Bi1/2(Na0.82K0.18)1/2TiO3 Ceramics
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概要
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Effects of BaTiO3 (BT) and BaZrO3 (BZ) modification on the crystal structure and electromechanical properties of lead-free Bi1/2(Na0.82K0.18)1/2TiO3 (BNKT) ceramics were compared within a doping range of 0--5 mol %. The differences between BT- and BZ-modification effects were clearly observed in polarization and electric field-induced strain hysteresis loops. BZ-modification induced a gradual transition from a ferroelectric to a nonpolar phase, resulting in an abnormal enhancement in the electric field-induced strain (EFIS) just after the transition. However, all BT-modified specimens showed strong ferroelectricity without abnormal enhancement in EFIS. The results suggest that Zr doping-induced B-site strains play a significant role in the ferroelectric-to-nonpolar phase transition in the Bi-perovskite.
- 2012-09-25
著者
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Kim Ill-won
Department Of Physics Ulsan University
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Hussain Ali
School of Nano & Advanced Materials Engineering, Changwon National University, Changwon 641-773, Republic of Korea
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Lee Jae-Shin
School of Materials Science and Engineering, University of Ulsan, Ulsan 680-749, Republic of Korea
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Ahn Chang-Won
Department of Physics, University of Ulsan, Ulsan 680-749, Republic of Korea
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Tran Vu
School of Materials Science and Engineering, University of Ulsan, Ulsan 680-749, Republic of Korea
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Han Hyoung-Su
School of Materials Science and Engineering, University of Ulsan, Ulsan 680-749, Republic of Korea
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Dinh Thi
School of Materials Science and Engineering, University of Ulsan, Ulsan 680-749, Republic of Korea
関連論文
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- Comparison of Ferroelectric and Strain Properties between BaTiO3- and BaZrO3-Modified Bi1/2(Na0.82K0.18)1/2TiO3 Ceramics