Crystal Field Splittings in Fe2+ Tutton Salts from Mössbauer Studies

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概要

• 論文の詳細を見る

• The Mössbauer spectra of Fe2+ Tutton salts, which form an isomorphous series of hydrated double sulphates having the general formula Fe(MSO4)2$\cdot$6H2O, $M$${=}$NH$_{4}^{+}$, K+, Rb+ and Cs+ have been studied over a temperature range from 77°–300°K. The data is analysed to assign characteristic temperatures of the $t_{2g}$ levels and find their splittings. It is concluded that the ground state wave function is singlet $|xy{>}$ in all these cases. Furthermore the effect of varying electronegativity of $M$ has negligible effect on isomer shift.

• Physical Society of Japanの論文
• 1968-01-05

著者

• Puri S.

  Department Of Physics University Of Rooke

• Chandra K.

  Department of Physics, University of Roorkee, Roorkee. (India)

• Chandra K.

  Department of Physics, University of Roorkee, Roorkee, India

• Puri S.

  Department of Physics, University of Roorkee, Roorkee. (India)

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• Mössbauer Studies of Chalcopyrite
• Crystal Field Splittings in Fe2+ Tutton Salts from Mössbauer Studies
• Mössbauer Studies of Chalcopyrite

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