Surface Instability in High Surface Area Complex Oxides: BaTiO3 Study
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概要
- 論文の詳細を見る
High quality BaTiO3 powders that were synthesized with hydrothermal and solid state methods are characterized with respect to surface chemistry. Different characterization techniques are used to obtain a physical picture for the BaTiO3 powders with respect to different synthesis routes and thermal histories. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS) are used to understand the BaTiO3 powders after heat and humidity treatments. Formation of amorphous and crystalline BaCO3 in local heterogeneous regions depletes the surrounding surface of Ba ions to create larger areas that are Ti-rich. BaCO3 formation and adventitious carbon adsorption occur extremely quickly on the surface of crushed single-crystal BaTiO3 powder, but for manufactured powders, the degree of carbonate formation and the impact on surface stoichiometry varies with thermal history.
- 2009-06-25
著者
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Randall Clive
Materials Research Institute The Pennsylvania State University
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CHAZONO Hirokazu
Taiyo Yuden Co., Ltd.
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Mizuno Youichi
Taiyo Yuden Co. Ltd. Gunma Jpn
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Mizuno Youichi
Taiyo Yuden Co., Ltd., Takasaki, Gunma 370-3347, Japan
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Chazono Hirokazu
Taiyo Yuden Co., Ltd., Takasaki, Gunma 370-3347, Japan
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Sakurai Nobuo
Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, U.S.A.
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Bojan Vincent
Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, U.S.A.
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Stapleton Josh
Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, U.S.A.
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Yang Gai-Ying
Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, U.S.A.
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Randall Clive
Material Research Institute, Pennsylvania State University
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Randall Clive
Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, U.S.A.
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