Surface-Modification on Vertical Alignment Layer Using UV-Curable Reactive Mesogens

概要

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The patterned vertical alignment (PVA) liquid crystal (LC) mode shows a wide viewing angle and a perfect dark state at a normal direction. However, it is inevitable to avoid the formation of disclinations and the movement of defect points during stabilization of LC’s reorientation. It is due to fact that the LC directors tilt downward in different directions with collisions between them by the fringe-electric field. Consequently, the transmittance decreases and the response time gets slower. In order to overcome this barrier, the pretilt angles in four different directions are introduced on the substrates utilizing UV-curable reactive mesogen (RM) monomers. According to our studies, concentration of RM, UV curing condition, and applied voltage to the cell are critical to achieve an optimized surface-modified PVA mode which provides the well-defined reorientation of the LCs with respect to an electric field. Moreover, morphological behaviors on surface of substrate depending on curing conditions were investigated in order to confirm the existence of the stabilized polymer.
2009-03-25