Flow Rate and Fluence Rate Dependences of the Triplet-State Lifetime of Talaporfin Sodium Photochemical Reaction in Flowing Solution

スポンサーリンク

概要

• 論文の詳細を見る

• The flow rate and fluence rate dependences of the triplet-state lifetime ($\tau_{\text{T}}$) and singlet oxygen (1O2) luminescence intensity of a Talaporfin sodium (mono-l-aspartyl chlorin e6, Laserphyrin\textregistered) photochemical reaction in a flowing solution were studied. The oxygen consumption rate constant ($k$) did not proportionally increase as the fluence rate increased. The relationship between the static oxygen concentration in the flowing solution and $\tau_{\text{T}}$ was estimated. $\tau_{\text{T}}$ at the fluence rate of $0.8\times 10^{4}$ W/m2 was 16% longer than that at $0.2\times 10^{4}$ W/m2 at the same oxygen concentration. The $\tau_{\text{T}}$ increase at the high-fluence rate is attributed to local and temporal oxygen depletion. The local and temporal oxygen depletion might cause the fluence-rate dependence nonproportionality of the measured $k$.

• 2007-03-15

著者

• Arai Tsunenori

  School Of Fundamental Science And Technology Graduate School Of Science And Technology Keio Universi

• Hakomori Shiho

  School Of Fundamental Science And Technology Graduate School Of Science And Technology Keio Universi

• Ohmori Sayaka

  School Of Fundamental Science And Technology Graduate School Of Science And Technology Keio Universi

• Arai Tsunenori

  School of Fundamental Science and Technology, Graduate School of Science and Technology, Keio University, Yokohama 223-8522, Japan

• Ohmori Sayaka

  School of Fundamental Science and Technology, Graduate School of Science and Technology, Keio University, Yokohama 223-8522, Japan

• Hakomori Shiho

  School of Fundamental Science and Technology, Graduate School of Science and Technology, Keio University, Yokohama 223-8522, Japan

関連論文

• A Comparative Study between Pulsed and Continuous Wave Irradiation for Talaporfin Sodium Mediated Photosensitization in Solution, In-Vitro and In-Vivo
• The Time-Resolved Phosphorescence Waveform Acquired from a Clinical Photosensitizer Using Temporal and Spectral Gating
• Prediction of Holmium-Yttrium-Aluminum-Garnet (Ho:YAG) Laser-Induced Bubble Dynamics in Whole Blood
• Flow Rate and Fluence Rate Dependences of the Triplet-State Lifetime of Talaporfin Sodium Photochemical Reaction in Flowing Solution

スポンサーリンク