Electrochromic Characteristics of a Nickel Borate Thin Film Investigated by In Situ XAFS and UV/vis Spectroscopy
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The electrochromic transition of a nickel borate thin film between colorless and brown was examined by means of in situ XAFS and UV/vis spectroscopy. The XAFS spectra showed that the average valence state of the nickel species in the film changed from +2.1 to +3.8 following the application of an electrode potential. Additionally, a broad peak at 700 nm was observed during in situ UV/vis absorption measurements on the application of a positive potential. These results suggest that the nickel borate film reversibly forms a NiOOH structure with a domain size of several nanometers during the electrochromic reaction.
- 公益社団法人 電気化学会の論文
公益社団法人 電気化学会 | 論文
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