[Cu(dmit)2]2− Building Block for Molecular Conductors and Magnets with Photocontrollable Spin Distribution

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概要

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• [Cu(dmit)2]2− formally consists of a magnetic Cu2+ ion (S = 1/2) and closed-shell π-conjugated dmit2− ligands. However, it has been determined by electron spin resonance and molecular orbital calculations that the majority (91–100%) of the spin delocalizes over the ligands in the ground state, while the spin significantly (40–90%) localizes on Cu under UV irradiation. Considering the results of X-ray structural analyses under UV irradiation, the spin distribution varies depending on the wavelengths irradiated and retaining the square-planar coordination geometries.

• 公益社団法人 日本化学会の論文

著者

• Naito Toshio

  Graduate School of Science and Engineering, Ehime University

• Noma Hiroki

  Graduate School of Science and Engineering, Ehime University

• Ohara Keishi

  Graduate School of Science and Engineering, Ehime University

関連論文

• [Cu(dmit)2]2− Building Block for Molecular Conductors and Magnets with Photocontrollable Spin Distribution

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