Decomposition of Chlorinated Hydrocarbons in Aqueous Solutions by Ultrasonic Irradiation.
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概要
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The decomposition of dilute chlorinated hydrocarbons, such as carbon tetrachloride, chlorobenezes, chlorophenoles and chloroacetaldehydes, in aqueous solution by high intensity ultrasonic irradiation were investigated. Besides chloroacetaldehydes, more than 85% of their initial amounts are rapidly decomposed in less than 1 hour. The major products were chloride anion, carbon monoxide, carbon dioxide and hydrogen. This reaction rate was accelerated under argon atmosphere. The sonolytical reactivity of these chlorinated hydrocarbons are influenced by their solubility in water and their volatility from water.
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