Long Time Hydrogen Evolution from Water Using Tris (2,2'-bipyridine) ruthenium (II)-methylviologen-platinum System as Visible-light Photocatalyst.
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Photo-evolution of hydrogen from water using tris (2, 2'-bipyridine) ruthenium (II) complex, methylviologen, disodium dihydrogenethylene-<I>N, N, N', N'</I>- tetraacetate and colloidal platinum was examined for long time over 14h. The evolution of hydrogen terminated at about 8 h in spite of presence of reactants. When solid ethylene-<I>N, N, N', N'</I>-tetraacetic acid was added to the system, the evolution of hydrogen proceeded over 14 h; added solid ethylene-<I>N, N, N', N'</I>-tetraacetic acid remained solid and the pH of the reaction solution was below 4.5 throughout the reaction.
- 一般社団法人 日本エネルギー学会の論文
一般社団法人 日本エネルギー学会 | 論文
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