Oxidation of NO to NO<SUB>2</SUB> in the Flue Gas (II):Oxidation by Addition of H<SUB>2</SUB>, H<SUB>2</SUB>O<SUB>2</SUB>, HCHO, CH<SUB>4</SUB>
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In this report, the reaction characteristics of O<SUB>2</SUB>-NO-H<SUB>2</SUB>, H<SUB>2</SUB>O<SUB>2</SUB>, HCHO, CH<SUB>4</SUB> systems were investigated, expecting the oxidation of NO to NO<SUB>2</SUB>. Main results were summerized as follows.<BR>1) These chemicals (H<SUB>2</SUB>, H<SUB>2</SUB>O<SUB>2</SUB>, HCHO, CH<SUB>4</SUB>) have the effect of oxidizing NO to NO<SUB>2</SUB> at 400-800°C in the presence of O<SUB>2</SUB> (only H<SUB>2</SUB>O<SUB>2</SUB> don't need the presence of O<SUB>2</SUB>)<BR>2) In the case of H<SUB>2</SUB>O<SUB>2</SUB> and HCHO, oxidation of NO to NO<SUB>2</SUB> was occured at [M] / [NO] _??_ ([M] / [NO] molar ratio of added chemicals to NO), but in the case of H<SUB>2</SUB> and CH<SUB>4</SUB> higher value of [M] / [NO] was needed.<BR>3) The important role of HO<SUB>2</SUB> radicals in oxidation of NO to NO<SUB>2</SUB> was recognized, from the kinetic model calculation including 22 species and 70 elementary reactions.
- 一般社団法人 日本エネルギー学会の論文
一般社団法人 日本エネルギー学会 | 論文
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