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Hydrogen shuttler reaction from one coal to another was carried out by the liquefaction of two coals which was mixed in apparently non donor condition. Coals had different donor ability which were confirmed by the reaction with benzophenone. The amount of transferred hydrogen from coal to benzophenone was calculated by the amount of diphenylmethane. The order of the hydrogen donor ability of coals were<BR>Miike coal>Taiheiyo coal>Yallourn coal<BR>By mixing Miike and Yallourn coal, positive effect of mixing on conversion was observed at nominal reaction time 0 min. Additivity was observed at nominal reaction time 60 min. By mixing Taiheiyo and Yallourn coal, inhibition effect on conversion was observed. These facts indicated the presence of hydrogen shuttler reaction between coals. The required amounts of hydrogen for coals in coal liquefaction were different. They might determine the effect of coal mixing on conversion.
- 一般社団法人 日本エネルギー学会の論文
一般社団法人 日本エネルギー学会 | 論文
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