Pioneering and Developing Exciplex Chemistry. Part3. Energy Gap Dependences of Electron Transfer Reactions and Their Roles as well as Roles of Solvent Dependent Exciplex Structures which are of Crucial Importance for Organic Photochemical Reaction Mechani
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概要
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A very broad and flat shape of the log <I>k</I><SUB>cs</SUB> vs. - Δ <I>G</I><SUB>cs</SUB> relation for the intermolecular electron transfer (ET) in the fluorescence quenching reaction in contrast to the bell-shaped log <I>k</I><SUB>CR</SUB> vs. - Δ <I>G</I><SUB>CR</SUB> relation of produced <SUP>1</SUP>LIP's (loose ion pairs) are discussed, leading to the mechanisms of the D, A distance distribution and formation of multiple IP states with different structures depending on the D, A interaction strength, solvation and - Δ G for ET. The solvent dependent structures and multiple states mechanisms derived here agree with the conclusions derived from the studies on exciplex phenomena as discussed in Part 2 and their roles of crucial importance in organic photochemical reactions are demonstrated.
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