New palladium-catalyzed addition of cyanotrimethylsilane to F-alkylated 1-aza-1,3-dienes. A convenient route to .BETA.,.GAMMA.-unsaturated .ALPHA.-F-alkyl-.ALPHA.-amino acid precursors.
スポンサーリンク
概要
- 論文の詳細を見る
2-<I>F</I>-Alkylated 1-aza-1,3-dienes, easily prepared from 1<I>H</I>-<I>F</I>-1-alkenephosphonates, smoothly underwent the addition of cyanotrimethylsilane in the presence of a catalytic amount of palladium(II) acetate or chloride to give β,γ-unsaturated α-<I>F</I>-alkyl-α-amino nitriles and/or γ-<I>F</I>-alkyl-γ-amino nitriles in good yields.
- 公益社団法人 日本化学会の論文
著者
関連論文
- μ-オキソ架橋型フタロシアニン類二量体の開発と応用 (特集 有機半導体材料)
- 金属フタロシアニン修飾キトサンの合成と生成ポリマーの触媒作用
- フタロシアニン系消臭剤の生分解性顆粒化および家庭用生ゴミ処理機への応用検討
- 羊毛およびセルロース誘導体粉末を用いた顆粒状消臭剤の作成
- μ-オキソ架橋型アルミニウムフタロシアニン・ガリウムフタロシアニンニ量体-合成, 結晶変態と電子写真感光体特性評価-
- [アミノ(カルボキシ)フタロシアニナト]コバルト(II)によるアセトアルデヒドの分解の電気化学的考察-新規フタロシアニン系消臭剤-
- μ-オキソ-金属(III)フタロシアニン二量体の新規結晶変態の探索と電子写真感光体としての特性評価
- 次世代対応フタロシアニン系消臭剤の工業化
- 次世代対応フタロシアニン系消臭剤の工業化 (特集「脱臭技術」最前線)
- 金属フタロシアニン系直接染料によるキチン/セルロース複合繊維の染色
- Subphthalocyanines Having Axial Substituent with Direct B-B Bond : General Preparation and Physical Properties
- Selected Papers : μ-Oxo-Bridged Subphthalocyanine Dimers : Preparation and Characterization by X-ray Structure Analysis
- Subphthalocyanine Derivatives Having a Phosphorus Group as an Axial Substituent
- μ-Oxo-Bridged Subphthalocyanine Dimers : Preparation and Characterization by X-ray Structure Analysis
- Solubility in Fluorinated Medium and Thermal Properties of Europium(III) Complexes with Phosphine Oxides
- Electrochemical Aspect of (Amino(carboxy)phthalocyaninato)cobalt (II) for the Effect on Decomposition of Acetaldehyde-New Type of Odor-remover Against Acetaldehyde Included in Tabacco Odor.
- Subphthalocyanine Derivatives Having a Phosphorus Group as an Axial Substituent
- .MU.-Oxo-Bridged Subphthalocyanine Dimers: Preparation and Characterization by X-ray Structure Analysis
- .MU.-Oxo-bridged Type Aluminum and Gallium Phthalocyanine Dimer. Synthesis, Polymorphs and Its Primary Evaluation as an Electrophotographic Receptor.
- Synthesis of New Polymorphos of .MU.-Oxo-metal(III) Phthalocyanine Dimers and Their Photoconductive Properties.
- New palladium-catalyzed addition of cyanotrimethylsilane to F-alkylated 1-aza-1,3-dienes. A convenient route to .BETA.,.GAMMA.-unsaturated .ALPHA.-F-alkyl-.ALPHA.-amino acid precursors.