不飽和カルボン酸化合物の固相反応の機構解析と可視化

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The mechanistic analysis and visualization of solid-state reactions of unsaturated carboxylic acid derivatives and the polymer crystals therefrom are described. We revealed a change in the crystal structures during the solid-state polymerization and the EZ isomerization of muconates on the basis of the results of X-ray single crystal structure analysis as well as powder X-ray diffraction measurements. We also describe the visualization of the processes of crystal phase transition and an intercalation reaction using the monomer and polymer crystals of unsaturated carboxylic acid derivatives.