ネットワークポリシランの改善された電解合成法
スポンサーリンク
概要
- 論文の詳細を見る
Orange network polysilanes; (MeSi)n, (BuSi)n, and (OctSi)n, were obtained by electrochemical reduction of methyltrichlorosilane, butyltrichlorosilane, and octyltrichlorosilane, respectively, in 1,2-dimethoxyethane using lithium perchlorate as the supporting electrolyte and careful isolation process to exclude linear-rich polymers. These orange polymers should have wider σ-conjugated systems than the previously reported yellow polymers. TEM observation of the resulting polymer revealed the existence of extremely large molecules as large as 0.1 to 2 µm in diameter.
- 公益社団法人 電気化学会の論文
著者
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Wakasa Masanobu
Department Of Chemistry Faculty Of Science Saitama University
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岡野 光俊
Department Of Nanochemistry Tokyo Polytechnic University
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山田 和洋
Department Of Nanochemistry Tokyo Polytechnic University
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HOSODA Nobutada
Department of Nanochemistry, Tokyo Polytechnic University
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中村 圭汰
Department of Nanochemistry, Tokyo Polytechnic University
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NAKAMURA Keita
Department of Nanochemistry, Tokyo Polytechnic University
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