接触グロー放電電解によるアルカンスルホン酸類水溶液の酸化分解

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概要

• 論文の詳細を見る

• Contact glow discharge electrolysis (CGDE) of alkanesulfonates in a neutral phosphate buffer solution was investigated. Methanesulfonic acid was oxidatively degraded to inorganic carbon and sulfate ion as the final products. Also in CGDE of ethanesulfonate and 1-propanesulfonate, the oxidation of alkyl and sulfo groups smoothly proceeded and various carboxylic acids such as oxalate and formate were found as the intermediate products. On the basis of product distribution and kinetic studies, it was assumed that hydroxyl radicals would play a crucial role in the oxidative degradation of aqueous alkanesulfonates.

• 公益社団法人 電気化学会の論文

著者

• 天野 亮

  Department of Material Science and Engineering, Graduate School of Engineering, Saitama Institute of

• 手塚 還

  Department of Material Science and Engineering, Graduate School of Engineering, Saitama Institute of

• 服部 美紀

  Department Of Material Science And Engineering Graduate School Of Engineering Saitama Institute Of Technology

• HATTORI Miki

  Department of Material Science and Engineering, Graduate School of Engineering, Saitama Institute of Technology

関連論文

• 接触グロー放電電解によるアルカンスルホン酸類水溶液の酸化分解
• 接触グロー放電電解によるベンゼンスルホン酸類水溶液の無機化処理
• Oxidative Degradation of Phenols by Contact Glow Discharge Electrolysis (論文特集号 電解科学技術の進展)
• 大気圧プラズマ中での亜酸化窒素の分解速度論
• 接触グロー放電電解によるアルカンスルホン酸類水溶液の酸化分解

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