Electrochemical Carboxylation of Aliphatic Ketones: Synthesis of β-Keto Carboxylic Acids

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概要

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• A constant current electrolysis of saturated aliphatic ketones in a CH3CN or DMF solution containing 0.1 mol dm−3 Bu4NBF4 with a platinum cathode and a magnesium anode under an atmospheric pressure of CO2 resulted in an efficient fixation of CO2 at α-position of carbonyl group in the ketones to give the corresponding β-keto carboxylic acids in moderate to good yields.

• 公益社団法人 電気化学会の論文

著者

• Fukuhara Tsuyoshi

  Laboratory Of Organic Reaction Division Of Chemical Process Engineering Graduate School Of Engineeri

• Hara Shoji

  Laboratory Of Organic Reaction Division Of Chemical Process Engineering Faculty Of Engineering Hokka

• Senboku Hisanori

  Laboratory Of Organic Reaction Division Of Chemical Process Engineering Faculty Of Engineering Hokka

• YAMAUCHI Yusuke

  Laboratory of Organic Reaction, Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University

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• Regioselective Electrochemical Carboxylation of Polyfluoroarenes
• Electrochemical Carboxylation of Aliphatic Ketones: Synthesis of β-Keto Carboxylic Acids

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