Electrochemical Impedance Study of Carbon-Supported Pt/Mo-Oxide for CO-Tolerant Anode Catalyst
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概要
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The CO-tolerance of a carbon-supported Pt/Mo-oxide (Pt/MoOx/C) anode in proton-exchange membrane fuel cells was examined by electrochemical impedance spectroscopy. A pseudo-inductive loop was clearly observed only for a Pt/MoOx/C anode at low anodic polarizations, which indicates the onset of the electro-oxidation of adsorbed CO (COad) on the Pt/MoOx/C catalyst. The CO-tolerance of Pt/MoOx/C at low anodic polarizations is mainly ascribed to the combination of the electro-oxidation of COad and the removal of CO by the water-gas shift reaction depending on the operating conditions.
- 公益社団法人 電気化学会の論文
著者
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IOROI Tsutomu
National Institute of Advanced Industrial Science and Technology
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YASUDA Kazuaki
National Institute of Advanced Industrial Science and Technology
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FUJIWARA Naoko
National Institute of Advanced Industrial Science and Technology (AIST), Research Institute for Ubiquitous Energy Devices
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YAMAZAKI Shin-ichi
National Institute of Advanced Industrial Science and Technology (AIST), Research Institute for Ubiquitous Energy Devices
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SIROMA Zyun
National Institute of Advanced Industrial Science and Technology (AIST), Research Institute for Ubiquitous Energy Devices
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IOROI Tsutomu
National Institute of Advanced Industrial Science and Technology (AIST), Research Institute for Ubiquitous Energy Devices
関連論文
- Dispersion Control of Nano-Particles and the Effect of the Coating Condition on the Performance of Proton-Exchange Membrane Fuel Cells (PEMFCs)
- Electrochemical Impedance Study of Carbon-Supported Pt/Mo-Oxide for CO-Tolerant Anode Catalyst