Studies on inorganic precipitate membranes: Membrane potential and bi-ionic potential.
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概要
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Electrical potentials arising across barium(II) phosphate, mercury(II) iodide and cobalt(II) chromate membranes using various 1:1 electrolytes are reported. Thermodynamically effective fixed charge density, which is an important parameter governing the membrane phenomena, has been evaluated by the theory of Toyoshima and Nozaki. Using the values of effective fixed charge density determined, the theory of bi-ionic potentials developed by Toyoshima and Nozaki based on the principles of the irreversible thermodynamics has been examined. Theoretical predictions were borne out quite satisfactorily by our experimental results.
- 公益社団法人 日本化学会の論文
著者
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Siddiqi Fasih
Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University
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Beg M.
Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University
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Singh Surendra
Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University
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Gupta Veena
Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University
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Prakash Poorna
Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University
関連論文
- Studies on inorganic precipitate membranes: Membrane potential and bi-ionic potential.
- Studies with parchment supported membranes. VIII. Determination of the thermodynamic effective fixed charge density of barium phosphate membrane by various methods and evaluation of permselectivity.