Interaction between aromatics and zinc chloride. II. The formation of .SIGMA.-complexes and cation radicals on supported zinc chloride.
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概要
- 論文の詳細を見る
Anhydrous zinc chloride supported in the solid state was found to produce colored intermediates by reactions with aromatics (anthracene, naphthacene, pentacene, pyrene, pelyrene, and chrysene) at 60 °C. The measurements of their electronic absorption spectra and ESR spectra confirmed that these were the same aromatics-zinc chloride σ-complexes and aromatics cation radicals as those formed in molten zinc chloride.
- 公益社団法人 日本化学会の論文
著者
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Morita Mikio
Government Industrial Development Laboratory
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Hirosawa Kunio
Government Industrial Development Laboratory
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Sato Toshio
Government Industrial Development Laboratory
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Ouchi Koji
Department of Applied Chemistry, Faculty of Engineering, Hokkaido University
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Sato Toshio
Government Industrial Development Laboratory, Hokkaido
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Hirosawa Kunio
Government Industrial Development Laboratory, Hokkaido
関連論文
- Interaction between aromatics and zinc chloride. III. The dissociation of triphenylmethane and 9,10-dihydroanthracene into ions.
- Interaction between aromatics and zinc chloride. II. The formation of .SIGMA.-complexes and cation radicals on supported zinc chloride.
- Interaction between aromatics and zinc chloride in the molten state. The formation of .SIGMA.-complexes and radicals.
- Infrared Absorption Spectra of Silica Gel-H216O, D216O, and H218O Systems