The heats of solution of optically active compounds and the corresponding racemic compounds.
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概要
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The heats of solution of crystalline amino acids and hydroxy acid in water at 298.15 K were measured with a twin isoperibol calorimeter. It was found, as was expected from the theory, that the difference in the heat of solution between optically active compounds and their corresponding racemic compounds was appreciably large compared with the heat of mixing of concentrated aqueous solutions of <I>d</I>- and <I>l</I>-optical isomers.
- 公益社団法人 日本化学会の論文
著者
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Matsumoto Masayuki
National Chemical Laboratory for Industry
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Amaya Kazuo
National Chemical Laboratory for Industry