Is O2*(a1.DELTA.g) formed in the O+O3,H+O3,and NO+O3 reactions?
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概要
- 論文の詳細を見る
An attempt was made to detect O<SUB>2</SUB><SUP>*</SUP>(a<SUP>1</SUP>Δ<SUB>g</SUB>) in the reactions of O+O<SUB>3</SUB>, H+O<SUB>3</SUB>, and NO+O<SUB>3</SUB> using a photoionization mass spectrometer. No significant signals for O<SUB>2</SUB><SUP>*</SUP>(a<SUP>1</SUP>Δ<SUB>g</SUB>) were observed in these reactions. From the results, it is concluded that less than 0.06, 0.001, and 0.002 of the reactive collisions result in the production of O<SUB>2</SUB><SUP>*</SUP>(a<SUP>1</SUP>Δ<SUB>g</SUB>) in the reactions of O+O<SUB>3</SUB>, H+O<SUB>3</SUB>, and NO+O<SUB>3</SUB> respectively, all at 298 K. The failure to observed O<SUB>2</SUB><SUP>*</SUP>(a<SUP>1</SUP>Δ<SUB>g</SUB>) in these reactions was discussed by means of correlation diagrams and GVB model representations.
- 公益社団法人 日本化学会の論文
著者
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AKIMOTO Hajime
The National Institute for Environmental Studies
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Washida Nobuaki
The National Institute for Environmental Studies
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Okuda Michio
The National Institute for Environmental Studies
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