Synthesis of cyclopentadecanone by ring contraction of cyclohexadecanone.

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概要

• 論文の詳細を見る

• Cyclopentadecanone has been synthesized from cyclohexadecanone. 2,2,15-Tribromocyclohexadecanone, upon treatment with sodium methoxide, underwent the Favorskii rearrangement <I>via</I> methyl 2-bromo-1-cyclopentadecene-1-carboxylate to produce a mixture of methyl 2-methoxy-1-cyclopentadecene-1-carboxylate, methyl 2-methoxy-2-cyclopentadecene-1-carboxylate, and methyl 2,2-dimethoxycyclopentadecane-1-carboxylate which was converted into cyclopentadecanone.

• 公益社団法人 日本化学会の論文

著者

• Miyake Akihisa

  Basic Research Laboratories, Toray Industries, Inc.

• Kondo Hisao

  Basic Research Laboratories, Toray Industries, Inc.

• Kondo Hisao

  Basic Research Laboratries, Toray Industries, Inc.

• Kato Tetsuya

  Basic Research Laboratories, Toray Industries, Inc.

• Kato Tetsuya

  Basic Research Laboratries, Toray Industries, Inc.

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• The crystal and molecular structure of 3-(1,4-epoxy-2-hydroxy-2,6,6-trimethylcyclohexyl)-1-methyl-2-propyl p-nitrobenzoate.
• Synthesis of cyclopentadecanone by ring contraction of cyclohexadecanone.
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