New effective nickel(II) catalysts for the cross-coupling of an aryl Grignard reagent with aryl halide.

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概要

• 論文の詳細を見る

• It has been found that seventeen nickel complexes of the Ni–O<SUB>4</SUB>, Ni–S<SUB>4</SUB>, Ni–O<SUB>2</SUB>N<SUB>2</SUB>, Ni–O<SUB>3</SUB>N<SUB>3</SUB>, Ni–N<SUB>4</SUB>, Ni–N<SUB>6</SUB>, and Ni–(C<SUB>5</SUB>)<SUB>2</SUB> types exhibit a high catalytic activity for the selective cross-coupling reaction of an aryl Grignard reagent with aryl iodide, which make possible the synthesis of unsymmetrical aromatics of a high purity and in a high yield.

• 公益社団法人 日本化学会の論文

著者

• Ibuki Eiichi

  Department of Organic Chemistry, Kyoto College of Pharmacy

• Ozasa Shigeru

  Department of Organic Chemistry, Kyoto College of Pharmacy

• Fujioka Yasuhiro

  Department of Organic Chemistry, Kyoto College of Pharmacy

• Okada Motofumi

  Department of Organic Chemistry, Kyoto College of Pharmacy

• Terada Katsutoshi

  Department of Organic Chemistry, Kyoto College of Pharmacy

関連論文

• Studies of Polyphenyls and Polyphenylenes. I. The Syntheses and Infrared and Electronic Spectra of Several Sexiphenyls
• Studies of polyphenyls and polyphenylenes. II. The synthesis and physical properties of polyphenyls containing para linkage.
• New effective nickel(II) catalysts for the cross-coupling of an aryl Grignard reagent with aryl halide.

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