Reaction of phenacyltriphenylarsonium bromides with N-methylaniline and N,N-dimethylaniline.

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概要

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• Reaction of phenacyltriphenylarsonium bromide with <I>N</I>-methylaniline furnished 2-phenylindole predominantly together with 1-methyl-2-phenylindole. The corresponding reaction of the arsonium salt with <I>N</I>,<I>N</I>-dimethylaniline did not give any indole, instead a simple nucleophilic substituted product, α-4′-(dimethylamino)deoxybenzoin was obtained. But, the latter reaction on being carried out in presence of hydrobromic acid afforded 1-methyl-2-phenylindole by the demethylation of <I>N</I>,<I>N</I>-dimethylaniline.

• 公益社団法人 日本化学会の論文

著者

• BANSAL Raj

  Department of Chemistry, University of Rajasthan

• Bansal Raj

  Department Of Chemistry University Of Rajasthan

• Bhagchandani Gope

  Department of Chemistry, University of Rajasthan

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