Synthetic photochemistry. XVIII. A sensitizer dependence in the photooxidation of indene and acenaphthylene. The occurrence of cis-1,2-glycol formation in a rose bengal-sensitized reaction.

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概要

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• Upon Rose Bengal-sensitized photooxygenation, indene and acenaphthylene afforded substantial amounts of the expected <I>cis</I>-glycols by means of the reduction of the intermediate dioxetanes. The formerly proposed structure of one of the isomeric methoxy hydroperoxides was revised on the basis of the chemical and spectral evidence.

• 公益社団法人 日本化学会の論文

著者

• Hatsui Toshihide

  Reaeseach Institute of Industrial Science, 86, Kyushu University

• Takeshita Hitoshi

  Reaeseach Institute of Industrial Science, 86, Kyushu University

関連論文

• Synthetic photochemistry. XVIII. A sensitizer dependence in the photooxidation of indene and acenaphthylene. The occurrence of cis-1,2-glycol formation in a rose bengal-sensitized reaction.

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