Moessbauer study of solid state photolysis of alkali tris(oxalato)ferrates(III).

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概要

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• Solid state photolysis of alkali tris(oxalato)ferrates(III) (Li, Na, K, Cs, and NH<SUB>4</SUB>) was studied with mercury radiation in the visible region by means of Mössbauer spectroscopy. The intermediate K<SUB>6</SUB>[Fe<SUB>2</SUB><SUP>11</SUP>(ox)<SUB>5</SUB>] is formed in the case of potassium tris(oxalato)ferrate (III) and FeC<SUB>2</SUB>O<SUB>4</SUB>·2H<SUB>2</SUB>O in the case of other alkali tris(oxalato)ferrates(III) [Li, Na, Cs, and NH<SUB>4</SUB>].

• 公益社団法人 日本化学会の論文

著者

• Brar Ajaib

  Chemistry Department, Guru Nanak Dev University

• Randhawa Balwinder

  Chemistry Department, Guru Nanak Dev University

関連論文

• Moessbauer studies of thermal decomposition of hexaamminecobalt(III) hexacyanoferrate(III) and hexaamminecobalt(III) hexachloroferrate(III) in air and in nitrogen atmosphere.
• Moessbauer study of solid state photolysis of alkali tris(oxalato)ferrates(III).

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