Mass spectral dehydration and decarboxylation in cyclic .ALPHA.-hydroxy acids, alcohols, and carboxylic acids.
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概要
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The relative ease of mass spectral de-carboxylation is greater than the ease of mass spectral dehydration as determined from a comparison of the alcohols <B>1a</B>–<B>4a</B> with acids <B>1b</B>–<B>4b</B>. However, the relative ease is reversed in α-hydroxy acids <B>2c</B>–<B>4c</B>; and dehydration predominates over decarboxylation.
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著者
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Patrick Timothy
Department of Chemistry, Southern Illinois University
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Akkari Khalid
Department of Chemistry, Southern Illinois University
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Matta Michael
Department of Chemistry, Southern Illinois University