Reaction between azibenzil and diarylmethanimine.

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概要

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• The thermal reaction of azibenzil with diarylmethanimine (<B>1</B>) leads to <I>N</I>-(diarylmethylene)diphenylacetamide (<B>2</B>) which from methanol or ethanol yields <I>N</I>-(α-alkoxydiarylmethyl)diphenylacetamide (<B>4</B>). The reduction of <B>2</B> with sodium borohydride gives <I>N</I>-(diarylmethyl)diphenylacetamide. The photochemical reaction of azibenzil and <B>1</B> results in the formation of cyano ethers besides the amido ethers <B>4</B>. A mechanism of formation of products is discussed.

• 公益社団法人 日本化学会の論文

著者

• Mehrotra Kailash

  Department of Chemistry, Banaras Hindu University

• Prasad Girija

  Department of Chemistry, Banaras Hindu University

関連論文

• Syntheses of N-substituted 3,3,4-triaryl- and 3,3,4,4-tetraphenyl-2-azetidinones.
• Novel and convenient synthesis of dioxaphospholes.
• Photochemical transformations of 1,2-diketones and benzhydrylamine.
• Reaction between azibenzil and diarylmethanimine.
• Cyclizations of dianions from 2-imino-1,2-diphenylethanone to oxazolines, oxazocines, and oxazonines.

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