The addition of (thioacyloxy)silanes to carbonyl compounds.
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概要
- 論文の詳細を見る
The reactions of (thioacyloxy)silane (<I>O</I>-trimethylsilyl thioacetate and thiobenzoate) with some aldehydes (propionaldehyde, butylaldehyde, and benzaldehyde) gave <I>S</I>-(1-substituted alkyl) thioacetates (<I>S</I>-[1-(trimethylsilyl-oxy)propyl, and -butyl] thioacetates, and <I>S</I>-[α-(trimethylsilyloxy)benzyl] thioacetate), and the three corresponding thiobenzoates respectively. The reactions were catalyzed by 1,8-diazabicyclo[5.4.0]undec-7-ene(DBU), and also by its salt with thiobenzoic acid.
- 公益社団法人 日本化学会の論文
著者
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Abe Yasuo
Radiation Center of Osaka Prefecture
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KAWAMURA Shunichi
Radiation Center of Osaka Prefecture
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Nakabayashi Takeshige
Radiation Center of Osaka Prefecture
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Horii Toyokazu
Radiation Center of Osaka Prefecture
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