Kinetics of the decarboxylation of benzylmalonic acid, ethylmalonic acid, and dimethylmalonic acid in hydroxylic solvents.

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概要

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• Kinetics of the decarboxylation of benzylmalonic acid, ethylmalonic acid, and dimethylmalonic acid have been shown to follow first order rate equation in several solvents, namely alkanediols and diethylene glycol (DEG), polyethylene glycol (PEG), and polypropylene glycol (PPG). The enthalpy and entropy of activation for the decarboxylation reactions were determined and the plot of Δ<I>H</I><SUP>\neweq</SUP> <I>vs.</I> Δ<I>S</I><SUP>\neweq</SUP> was found to be linear through all the solvents.

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著者

• Majumdar Dilip

  Department of Chemistry, University of Kalyani

• Biswas Mihir

  Department of Chemistry, University of Kalyani

関連論文

• Kinetics of the decarboxylation of benzylmalonic acid, ethylmalonic acid, and dimethylmalonic acid in hydroxylic solvents.

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