ESR Spectra and structure of the radical anions of organo halosilanes.

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概要

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• The radical anions of ethyl- and vinyl- halosilanes formed in solid matrices of tetramethylsilane and their ESR spectra were investigated to be compared with results obtained from related radical anions. These radical anions have a trigonal bipyramidal structure with two axial and two equatorial positions. Ethyl and methyl groups which are less electronetative than H prefer the equatorial positons. The vinyl group with a single π electron system occupies the equatorial position due to its electron-donating capability, in spite of its larger electronegativity.

• 公益社団法人 日本化学会の論文

著者

• Hasegawa Akinori

  Department Of Chemistry Kogakkanuniversity

• Hayashi Michiro

  Department of Chemistry, Faculty of Science, Hiroshima University

• Nagayama Akihiro

  Department of Chemistry, Faculty of Science, Hiroshima University

関連論文

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• ESR Spectra and structure of the radical anions of organo halosilanes.
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• Vibrational Assignments of Ethylmethylsilane
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• Rotational Isomerism in Ethylmethylsilane
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• An ESR Study of Diborane Anion Radicals in the Adsorbed State
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• The Electron Spin Resonance of the Mn2+ Ion in Aqueous Surfactant Solutions
• Rotational Isomerism in Epihalogenohydrin

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