Linear solvation energy relationships. 18. Solvent effects on the electronic absorption spectrum of p-nitrophenoxide ion.

スポンサーリンク

概要

• 論文の詳細を見る

• A quantitative analysis of the effects of hydroxylic and aprotic solvents on the electronic absorption spectrum of 4-nitrophenoxide anion is described. By means of linear solvation energy relationships, the contributions of solvent dipolarity, polarizability, and hydrogen bonding are assessed. A significant conclusion is that ion-pairing strongly influences the 4-nitrophenoxide ion in aprotic solvents, but not in hydroxylic solvents. In the latter, specific solvation of both the nitro group and the phenoxide ion center are important.

• 公益社団法人 日本化学会の論文

著者

• Taft Robert

  Department Of Chemistry University Of California

• Abboud José-Luis

  Départment de Chimie, Faculte des Sciences, Université Cadi Ayyad

• Kamlet Mortimer

  Naval Surface Weapons Center, White Oak Laboratory

関連論文

• Semiempirical (AM1) Studies of Possible and Preferred Site(s) of Porotnation in the Gas Phase for Polyfunctional Nitrogen Bases: N^1, N^1 -Dimethyl-N^2-azinylformamidines
• Linear solvation energy relationships. 18. Solvent effects on the electronic absorption spectrum of p-nitrophenoxide ion.

スポンサーリンク