Preferential crystallization of 2-amino-2-phenylethanol and its application as a resolving agent.
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概要
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(±)-2-Amino-2-phenylethanol (phenylglycinol) prepared from (±)-2-amino-2-phenylacetic acid (DL-phenylglycine) by lithium aluminium hydride reduction was efficiently resolved into a pair of optically active forms by preferential crystallization. The optically active amino alcohol was successfully applied as a basic resolving agent to the resolution of tartaric acid, 2-hydroxy-2-phenylpropionic acid, 2-hydroxy-3-phenylpropionic acid, 2-phenylpropionic acid, and 2-phenyl-2-ureidoacetic acid.
- 公益社団法人 日本化学会の論文
著者
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NOHIRA Hiroyuki
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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Saigo Kazuhiko
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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- Preferential crystallization of 2-amino-2-phenylethanol and its application as a resolving agent.