Phosphatosulfates. Metal-ion effects on the acid-catalyzed hydrolysis of phenyl phosphatosulfate in an acetonitrile-water mixed solvent.

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概要

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• The rates of the acid-catalyzed hydrolysis of phenyl phosphatosulfate (PPS) have been found to be highly dependent on the water content in the mixed solvent of acetonitrile–water. A remarkable rate acceleration was observed with a rate maximum near the 1 : 1 ratio of PPS and metal ion, and with a solvent with a low water content. Under such conditions, the site of the cleavage of the P–O–S linkage was observed to be predominantly the S–O bond.

• 公益社団法人 日本化学会の論文

著者

• Asai Yoshio

  Department of Chemistry, Faculty of Engineering, Gunma University

関連論文

• Phosphatosulfates. Metal-ion effects on the acid-catalyzed hydrolysis of phenyl phosphatosulfate in an acetonitrile-water mixed solvent.

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