Room-temperature fluorine addition to fluoro-substituted naphthalene derivative using xenon difluoride.

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概要

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• Room-temperature boron trifluoride catalyzed addition of fluorine to octafluoronaphthalene with xenon difluoride proceeds as 1,4- and 1,2-addition, giving decafluoro-1,4-dihydronaphthalene and decafluoro-1,2-dihydronaphthalene. Fluorine addition to 2-methoxy- and 2-ethoxyheptafluoronaphthalene gave only 1,4-adducts, while reaction with 2-isopropoxyheptafluoronaphthalene resulted in octafluoro-1,2-dihydronaphthalene-2-one and 6-isopropoxynonafluoro-1,4-dihydronaphthalene.

• 公益社団法人 日本化学会の論文

著者

• Zupan Marko

  "Jozef Stefan" Institute and Department of Chemistry, "E. Kardelj" University of Ljubljana

• Zajc Barbara

  "Jozef Stefan" Institute and Department of Chemistry, "E. Kardelj" University of Ljubljana

• Zupan Marko

  "Jozef Stefan" Institute and Department of Chemistry, "E. Kardelj" University of Ljubljana

• Zajc Barbara

  "Jozef Stefan" Institute and Department of Chemistry, "E. Kardelj" University of Ljubljana

関連論文

• Room-temperature fluorine addition to fluoro-substituted naphthalene derivative using xenon difluoride.

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