Multidentate ligand kinetics. IV. Computer simulation of the steady state of the free ligands in a coordination chain reaction.
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概要
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The ligand-substitution reactions between two multidentate ligand complexes in the presence of free ligands proceed by means of a coordination chain-reaction mechanism. The reaction was simulated on a computer under various conditions. The character of the steady state of the free ligands in the coordination chain reaction was discussed. The conditions under which the coordination chain reaction proceeds with the steady state of the free ligands were determined. The diagrams of the time development of the free ligands were found to be useful for studies using the coordination chain reaction.
- 公益社団法人 日本化学会の論文
著者
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Kumai Toshihiko
Department of Basic Technology, Faculty of Engineering, Yamagata University
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Katsuyama Tetsuo
Department of Basic Technology, Faculty of Engineering, Yamagata University
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