The interaction of a neutral polymer with small ions in solution. I. A method for the analysis of ion binding to a neutral polymer.

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概要

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• A method for the analysis of ion binding to a neutral polymer, such as poly(oxyethylene) (POE), based on the one-dimensional lattice model has been proposed. The grand partition function for the one-dimensional lattice has been given by the product of the statistical weight matrix. Interaction between the ions bound to the lattice points has been well approximated by the Debye-Hückel pair-by-pair potential, and the distance between the bound ions has been assumed to be the root mean square end-to-end distance of the partial chain. Based on the model, an equilibrium constant has been defined which is referred to the <I>binding constant</I>.

• 公益社団法人 日本化学会の論文

著者

• Murakami Kenkichi

  Chemical Research Institute Of Non-aqueous Solutions

• Ono Katsumichi

  Chemical Research Institute of Non-Aqueous Solutions, Tohoku University

• Awano Hiroshi

  Chemical Research Institute of Non-Aqueous Solutions, Tohoku University

関連論文

• Structure and Properties of Degradative Crosslinked Amorphous Polymer Materials : Single Degradation of Crosslinked Polymers. Part I
• The interaction of a neutral polymer with small ions in solution. II. The binding of alkali metal ions to poly(oxyethylene) in several organic solvents.
• The interaction of a neutral polymer with small ions in solution. I. A method for the analysis of ion binding to a neutral polymer.
• The interaction of a neutral polymer with small ions in solution. III. Ionic association on a poly(oxyethylene) chain.

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