Fluoride salts on alumina as reagents for alkylation of phenols and alcohols.
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概要
- 論文の詳細を見る
The effectiveness of alkali metal fluorides impregnated on alumina as a reagent for promoting alkylation was optimized with respect to the metal cation, the amount of impregnation, and the reaction solvent. Potassium or caesium fluoride on alumina in acetonitrile or 1,2-dimethoxyethane was concluded to be the best reaction system for general use. <I>O</I>-Alkylation of substituted phenols, primary and secondary alcohols, and a glycol was carried out mostly in good yields under mild conditions with simple experimental procedures.
- 公益社団法人 日本化学会の論文
著者
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Ando Takashi
The Institute of Scientific and Industrial Research, Osaka University
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Yamawaki Junko
The Institute of Scientific and Industrial Research, Osaka University
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Hanafusa Terukiyo
The Institute of Scientific and Industrial Reasearch, Osaka University
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Kawate Takehiko
The Institute of Scientific and Industrial Research, Osaka University
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Sumi Shinjiro
The Institute of Scientific and Industrial Research, Osaka University
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