The disproportionation of cis-bicyclo(4.3.0)nona-3,7-diene catalyzed by Fe(CO)5 and Cp2Fe2(CO)4.

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概要

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• <I>cis</I>-Bicyclo[4.3.0]nona-3,7-diene (<B>1</B>) was catalytically disproportionated by the use of Fe(CO)<SUB>5</SUB> and Cp<SUB>2</SUB>Fe<SUB>2</SUB>(CO)<SUB>4</SUB> to bicyclo[4.3.0]non-1(6)-ene (<B>3</B>) and indan (<B>4</B>). However, the same reaction catalyzed by the use of other metal carbonyls gave merely small amounts of <B>3</B> and <B>4</B>, while those using Pd– and Rh–carbons yielded only <B>4</B> and the starting material, <B>1</B>, respectively.

• 公益社団法人 日本化学会の論文

著者

• Ishii Yasutaka

  Department Of Applied Chemistly Faculty Of Engineering Kansai University

• Ogawa Masaya

  Department Of Neurology Aomori Prefectural Central Hospital

• Okabayashi Shinji

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

• Amaike Yoichi

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

• Kagayama Takashi

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

• Matsukawa Yasuo

  Department of Applied Chemistry, Faculty of Engineering, Kansai University

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