Salt effects on the intramolecular Cannizzaro reaction of phenylglyoxal. Specific acceleration by calcium ion.
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概要
- 論文の詳細を見る
Effects of added salts on the rate of alkaline rearrangement of phenylglyoxal to mandelic acid were examined in aqueous solution at 30 °C. The reaction showed positive salt effects. Specific acceleration was found with some metal ions, the efficiency decreasing in the order Ca<SUP>2+</SUP>>Tl<SUP>+</SUP>>Sr<SUP>2+</SUP>>Ba<SUP>2+</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Fueno Takayuki
Faculty Of Engineering Science Osaka University
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Okuyama Tadashi
Faculty Of Engineering Science Osaka University
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Kimura Kazumasa
Faculty of Engineering Science, Osaka University
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