Crystal and molecular structure of (11,13-dimethyl-12-(p-methylbenzoyl)-1,4,7,10-tetraaza-10,12-cyclotridecadienato)nickel(II) hexafluorophosphate.

スポンサーリンク

概要

• 論文の詳細を見る

• The title complex prepared through an electrophilic substitution of (11,13-diemthyl-1,4,7,10-tetraaza-10,12-cyclotridecadienato)nickel(II) bromide with <I>p</I>-methylbenzoyl chloride was subjected to single-crystal X-ray diffraction analysis. The analysis has revealed completion of the substitution reaction, pseudo C<SUB>2</SUB> symmetry of the macrocyclic complex minus the substituent, and an essentially square planar coordination environment with slight tetrahedral distortion. The substituted <I>p</I>-methylbenzoyl group is tilted with respect to the least-squares plane of the conjugated six-membered chelate ring, where the dihedral angle between them is 69.2°.

• 公益社団法人 日本化学会の論文

著者

• Matsumoto Naohide

  Department of Industrial Chemistry, Faculty of Engineering, Kumamoto University

関連論文

• Crystal and molecular structure of (11,13-dimethyl-12-(p-methylbenzoyl)-1,4,7,10-tetraaza-10,12-cyclotridecadienato)nickel(II) hexafluorophosphate.

スポンサーリンク