Polarized Raman spectrum of maleic anhydride crystal.
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概要
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The polarized Raman spectrum of the maleic anhydride single crystal was studied. Prominent polarization behavior of the Raman bands was observed. Assuming the oriented gas model, the relative intensities of the non-totally symmetric intramolecular vibrations in various polarized Raman spectra were studied based on the data of the crystal structure. The assignments of the fundamental vibrational frequencies for maleic anhydride were reinvestigated through the polarization behavior of the Raman bands as well as the normal coordinate calculation.
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